1.  Introduction 
                    This paper gives an overview of the present  status of non-conventional energy sources of India, world geothermal resources,  its advantages over other conventional energy sources, various uses and  technologies involved in utilizing this energy source. Exploration methods used  to assess the resources are explained in brief. Various geothermal provinces of  India  and their power generating /direct use potential are described in detail. 
                  
                    2. Advantages of Geothermal Energy  
                  Geothermal energy is a domestic energy resource  with cost, reliability and environmental advantages over conventional energy  sources. It contributes both to energy supply,with electrical power  generation and direct-heat uses. 
                  
                    For generation of electricity, hot water is  brought from the underground reservoir to the surface through production wells,  and is flashed to steam in special vessels by release of pressure. The steam is  separated from the liquid and fed to a turbine engine, which turns a generator.  Spent geothermal fluid is injected back into peripheral parts of the reservoir  to help maintain reservoir pressure.  In the absence of steam, heat from  hot water is extracted through a secondary fluid and the high pressure vapour  from the secondary fluid is utilized to run the turbine. 
                  
                    If the reservoir is to be used for direct-heat  application, the geothermal water is usually fed to a heat exchanger and  the heat thus extracted is used for home heating, greenhouse, vegetable drying  and a wide variety of other small scale industries. Hot water at temperatures  less than 120oC can be used for this purpose.  Further, the  spent hot water, after generating electricity can also be used for direct  application. 
                  
                    As a result of today's geothermal production,  consumption of exhaustible fossil fuels is offset, along with the release of  acid-rain and greenhouse gases that are caused by fossil-fuel use. Systems for  use of geothermal energy have proven to be extremely reliable and flexible.  Geothermal electric power plants are on line 97% of the time, whereas  nuclear plants average only 65% and coal plants only 75% on-line time.  Geothermal plants are modular, and can be installed in increments as needed. Because  they are modular, that can be transported conveniently to any site. Both  baseline and peaking power can be generated. Construction time can be as little  as 6 months for plants in the range 0.5 to 10 MW and as little as 2 years for  clusters of plants totaling 250 MW or more. 
                  
                  The competing goals of increased energy production for  worldwide social development and of mitigating release of atmosphere-polluting  gases are not compatible using today's fuel mix, which relies heavily on coal  and petroleum. Development of geothermal energy has a large net positive impact  on the environment compared with development of conventional energy sources.Geothermal power plants have sulphur-emissions rates that average only a  few percent of those from fossil-fuel alternatives. The newest generation of  geothermal power plants emits only ~135 gm of carbon (as carbon dioxide) per  megawatt-hour (MW-hr) of electricity generated. This figure compares with 128  kg /MW-hr of carbon for a plant operating on natural gas (methane) and 225  kg/MW-hr of carbon for a plant using bituminous coal. Nitrogen oxide emissions  are much lower in geothermal power plants than in fossil power plants.  Nitrogen-oxides combine with hydrocarbon vapours in the atmosphere to produce ground-level  ozone, a gas that causes adverse health effects and crop losses as well as  smog. There are other environmental advantages to geothermal energy. Geothermal  power plants require very little land, taking up only a fraction of that needed  by other energy sources.  Thus emission of  CO2  and SO2 by geothermal power plants is far less compared with  conventional fossil fuel based power plants (Below Figure). 
                    
                  Emission of CO2 and SO2  by geothermal and conventional power plants. 
                   
                      
                    
                  3.  Present Status of Non-conventional Energy Resourses In INDIA: 
                  The estimated power shortage in India in the next five years  will be 43,000 MW while the total potential of non-conventional energy is about  50,000 MW. The power production status of non-conventional energy in India is shown in  Table  
                  Table  Shows Power production status of non-conventional energy in India 
                      (Chandrasekharam, 2000) 
                        ________________________________________________________________________   
                       Renewable  Power                          Potential                        Achieved 
                       ---------------------------------------------------------------------------------------------  
                       Wind  Power                                 20,000  MW                     1,000 MW 
                       Small  Hydro Power                      10,000  MW                      172 MW 
                       Biomass                                          20,000  MW                      141 MW 
                       Solar  photo-voltaic Power        20 MW/sq.km                  810 KW 
                  Geothermal energy is not included here, although  it has an estimated potential of about 10,000 MW (Ravi Shankar, 1996). The  PPs (Independent Power Producers) are not aware of this potential and the  country is not keen in developing this source due to the availability of 190 billion tones of recoverable coal resources which is supporting coal based power projects and hampering the healthy growth  of non-conventional energy program. 
                  
                  Excessive use of this source without adopting  strategies to mitigate its effects will have deteriorating effect on the  quality of human life. In another decade emission of CO2 , SO2  and Nx will exceed 1500 million tones, 1900 kilo tones and 1200 kilo tones  respectively (World Bank Report 1999). This means CO2  emissions will  be 775 million metric tones per year as compared to 1000 million metric tones per  year produced in the entire European Union!  No doubt the cost of  electricity produced from coal is far less expensive compared with other fuels.  The present day cost of one unit of power is less than a rupee in the case of  coal based power while liquid fuel based power costs about Rs. 2 per unit  (Mehta, 1999) and hydro power costs about Rs. 1.50 (World Bank Report, 1999).  But the expenditure spent to meet the consequences (like disposal of fly ash;  treating the coal with high ash content etc) is high which automatically  increases one rupee a unit to several rupees. The ash content in Indian coal is  about 45% and the annual production of fly ash is about 75 million tons and it  may cross 100 million marks very shortly. (Chandrasekharam, 2000). Only 5% of this  ash is being utilized at present.  
                  
                    The reasons for low targets (as shown in above table) achieved  through non-conventional energy sources are many. For example, solar  photo-voltaic (SPV) and solar thermal are far less economically attractive than  conventional technologies for, the current estimated cost of SPV modules are  around $ 4 to 5 Wp (peak watt). Assuming the cost to decline by 50% in future,  the estimated cost would be around $2.5Wp which is highly uncompetitive  compared with $ 1.05 for other conventional sources.  In the case of wind  power, operational problems in matching demand and supply exists since the wind  velocity is seasonal (World Bank Report, 1999). The estimated cost of power  produced using geothermal resources is less than Rs. 2 /kWh (Entingh et al., 1994). 
                  
                  In future India has to fall in line with  other countries in controlling emission of CO2, SO2   and Nx into the atmosphere and thus has to depend on cheap,  environmentally clean geothermal energy resources. 
                  
                    4.  Resources definition: 
                    Geothermal energy, in the broad sense, is the  heat in the earth and released by conduction at an average heat flux of 60 MW/m2 .  The four prerequisites necessary to exploit geothermal energy are (Economides  and Ungemach, 1987): 
                  
                    a).  A heat source which could be a magma  body, or a simple hot rock at depth, b) Heat carrier fluid, c) Permeable or  fractured rock acting as a reservoir and d) Cap rocks providing an impermeable  and insulating cover. 
                  
                    The most obviously usable geothermal resources  require convective heat transfer i.e. presence of fluid. This occurs at a  limited number of locations. When ever conduction alone prevails (any where) heat  recovery requires that a fluid be forced through a large fractured heat  exchange area to sweep the energy stored in the rocks at depth. This is  basically the concept of hot dry rock technology, which is very promising.  Hydrothermal resources are classified according to the specific enthalpy of the  fluid. Waters with temperatures between 30 - 120oC are called low enthalpy  resources (0.03 to 0.4MJ/kg); Waters with temperatures above 120oC  are termed as high enthalpy fluids (0.5 to 3MJ/kg).  
                  
                    Location of geothermal provinces is dictated by  the geodynamic model of the earth's crust, known as the global plate tectonics.  This theory accounts for the most of the geodynamic processes affecting the  earth's crust.  These geodynamic processes include subduction, subsidence,  uplift, fracturing etc. These occurrences result in associated geothermal  features such as the distribution of heat flow, active tectonics, volcanism and  hydrothermal convection. 
                   Table Showing World Geothermal Energy Production  
                    _________________________________________________________________ 
                    Country                   1990 (MW installed)                 2005 (MW installed) 
                    --------------------------------------------------------------------------------------------------------- 
                     USA                                            2775                                                     2554 
                    Philippines                                   891                                                     1931 
                    Italy                                              545                                                       790 
                    Indonesia                                     145                                                       797 
                    Japan                                            215                                                       535 
                    New Zealand                                283                                                       445 
                    Iceland                                            45                                                        202 
                    Costa Rica                                        0                                                        163 
                    El  Salvador                                      95                                                       151 
                    China                                                19                                                          28 
                    Guatemal                                           0                                                            2 
                  Turkey                                             20                                                          93 
                  ----------------------------------------------------------------------------------------------------------- 
                    Total                                             5033                                                      7691 
                    ___________________________________________________________________ 
                   
                  5.  World geothermal energy status 
                  Currently  there are an estimated 12,000 MW of direct use and over 8,000 MW of generating  capacity in geothermal resources world-wide. To put geothermal generation into  perspective, this generating capacity is about 0.4% of the world total  installed generating capacity. The USA,  Philippines, Italy, Mexico,  Iceland Indonesia, Japan and  New Zealand  are the largest users of geothermal energy resources (both direct and  indirect). Table  showing the status of present electric power generation from  geothermal energy in order of size per country. The 1999 capacity of 8246MW  electricity was a 40% increase from the capacity installed in 1990.    
                  
                    Other countries with less than 20 MW generations are: Argentina, Australia Ethiopia, France (Guadeloupe), Greece,  Portugal (Azores), Russia, Thailand (World Geothermal Congress,  2000). Currently  geothermal resources in over 30 countries provide directly used heat capacity  of over 12,000 MW. These countries include: Algeria,  Austria, Belgium, Bulgaria,  China, Denmark, England,  France, Georgia, Germany,  Greece, Hungary, Iceland,  Indonesia, Ireland, Italy,  Japan, Latvia, Nicaragua,  Philippines, Poland, Portugal,  Romania, Russia, Slovakia,  Sweden, Switzerland, Thailand  and Turkey.  
                  
                    The  majority of the earlier geothermal plants were funded and operated by National  Power agencies around the world with the exception of California where the development of the  Geysers geothermal field was carried out by privately funded utility companies.  With the recent international trend towards de-regulation in the power  industry, private developers have become more directly involved in both  resource assessment and development. This has been particularly so in Indonesia and the Philippines.  
                  
                    The  world map (shown below) illustrates where geothermal resources are currently being  utilised. The red dots indicate power generation which includes small scale,  rural development as well as large scale power plants. Direct use is also  applicable to the red dots. The blue dots indicate both high temperature and  medium to low temperature resources where direct use of the geothermal heat is  being applied. The yellow dots indicate World Bank funded projects, and the  green dots indicate Hot Dry Rock (HDR) research is underway.  
                  Geothermal  energy utilization map of the world 
                    
                   
                  Flash steam plants totally dominate the  marketplace, but over the past ten years many smaller scale binary cycle plants  have been installed while several combined (flash steam/binary plants) have  been installed. The majority of the World's geothermal power stations are base  load stations meaning that they operate 24 hours a day for 365 days. To  allow for a load factor of about 80% and an average steam cost of Rs. 2 per kWh  geothermal power. 
                  
                    6.  Technology and Resource Type  
                    Geothermal resources vary in temperature from  30-350oC, and can either be dry, mainly steam, a mixture of steam  and water or just liquid water. In order to extract geothermal heat from the  earth, water is the transfer medium. Naturally occurring groundwater is  available for this task in most places but more recently technologies are being  developed to even extract the energy from hot dry rock resources. The  temperature of the resource is a major determinant of the type of technologies  required to extract the heat and the uses to which it can be put. The Table 3 lists  the basic technologies normally utilized according to resource temperature.
                                   
                  Table  shows commonly used Basic technology for power generation 
                  
                    
                      Reservoir Temperature
  | 
                      Reservoir Fluid  | 
                      Common Use  | 
                      Technology commonly chosen  | 
                     
                    
                      High Temperature >220oC  | 
                      Water or Steam  | 
                      Power Generation Direct    Use  | 
                      Flash Steam; Combined (Flash and Binary) Cycle  
                      Direct Fluid Use Heat Exchangers Heat Pumps   | 
                     
                    
                      Intermediate Temperature 100-220oC.  | 
                      Water  | 
                      Power Generation Direct    Use  | 
                      Binary Cycle  
                      Direct Fluid Use; Heat Exchangers ;  Heat Pumps   | 
                     
                    
                      Low Temperature 50-150oC  | 
                      Water  | 
                      Direct Use  | 
                      Direct Fluid Use; Heat Exchangers; Heat Pumps   | 
                     
                   
                  7.   Power  Generation Technology 
                       7.1 High Temperature Resources  
                  High  temperature geothermal reservoirs containing water and/or steam can provide  steam to directly drive steam turbines and electrical generation plant. More  recently developed binary power plant technologies enables more of the heat  from the resource to be utilised for power generation. A combination of  conventional flash and binary cycle technology is becoming increasingly  popular.                   
                   
                  High  temperature resources commonly produce either steam, or a mixture of steam and  water from the production wells. The steam and water is separated in a pressure  vessel (Separator), with the steam piped to the power station where it drives  one or more steam turbines to produce electric power. The separated geothermal  water (brine) is either utilised in a binary cycle type plant to produce more  power, or is disposed of back into the reservoir down deep (injection) wells.  The following is a brief description of each of the technologies most commonly  used to utilise high temperature resources for power generation.                   
                   
                    Flash Steam Power Plant 
                  This is the most common type of geothermal power  plant. The illustration below shows the principal elements of this  type of plant. The steam, once it has been separated from the water, is piped  to the powerhouse where it is used to drive the steam turbine. The steam is  condensed after leaving the turbine, creating a partial vacuum and thereby  maximizing the power generated by the turbine-generator. The steam is usually  condensed either in a direct contact condenser, or a heat exchanger type  condenser. In a direct contact condenser the cooling water from the cooling  tower is sprayed onto and mixes with the steam. The condensed steam then forms  part of the cooling water circuit, and a substantial portion is subsequently  evaporated and is dispersed into the atmosphere through the cooling tower.  Excess cooling water called blow down is often disposed of in shallow injection  wells. As an alternative to direct contact condensers shell and tube type  condensers are sometimes used, as is shown in the schematic below. In this type  of plant, the condensed steam does not come into contact with the cooling  water, and is disposed of in injection wells.
                     
                  
                    Typically,  flash condensing geothermal power plants vary in size from 5 MW to over 100 MW.  Depending on the steam characteristics, gas content, pressures, and power plant  design, between 6000 kg and 9000 kg of steam each hour is required to produce  each MW of electrical power. Small power plants (less than 10 MW) are often  called well head units as they only require the steam of one well and are  located adjacent to the well on the drilling pad in order to reduce pipeline  costs. Often such well head units do not have a condenser, and are called  backpressure units. They are very cheap and simple to install, but are  inefficient (typically 10-20 tonne per hour of steam for every MW of  electricity) and can have higher environmental impacts. 
                    
                   
                  Binary Cycle Power Plants 
                    In  reservoirs where temperatures are typically less than 220oC. but  greater than 100oC binary cycle plants are often utilised. The  illustration below shows the principal elements of this type of plant.  The reservoir fluid (either steam or water or both) is passed  
                  
   
                  Binary cycle type plants are usually between 7  and 12 % efficient, depending on the temperature of the primary (geothermal)  fluid. Binary Cycle plants typically vary in size from 500 kW to 10 MW. The  curves in the below graph is give an indication of the electrical power output  from a binary plant over a range of flows and geothermal reservoir  temperatures. 
                  
                    Combined Cycle  (Flash and Binary) 
                      Combined Cycle power plants are a combination of  conventional steam turbine technology and binary cycle technology. By combining  both technologies, higher overall utilization efficiencies can be gained, as  the conventional steam turbine is more efficient at generation of power from  high temperature steam, and the binary cycle from the lower temperature  separated water. In addition, by replacing the condenser-cooling tower cooling  system in a conventional plant by a binary plant, the heat available from  condensing the spent steam after it has left the steam turbine can be utilized  to produce more power.  
                    
                  
                    7.2   Medium Temperature  Resources  
                  Medium  temperature resources are normally hot water with temperatures ranging from 100oC to 220oC. The most common technology for utilising such resources  for power generation is the binary cycle technology. This technology is  described above under high temperature resources.  
                  
                    8.  Direct  Use Technology 
                  Direct  use technologies are where geothermal heat is used directly rather than for  power generation and are built around the extraction of heat from relatively  low temperature geothermal resources, generally of less than 150oC.  Because geothermal heat is non-transportable, (except short distances by fluid  pipeline) any applications must generally be sited within 10 km or less of the  resource. 
                  
  For many resources, the relatively low temperatures  and/or pressures in the reservoirs means that they have insufficient energy  and/or pressure differences to naturally carry the fluids to the surface and  pumps are frequently used (either down-hole or at the surface).  
                  
                  The  type of technology selected for utilising geothermal heat for direct use  applications is dependent on the nature of the geothermal fluid and the type of  direct use planned. In many direct use applications, the geothermal fluid  cannot be used directly, such as in drying processes or where clean steam or  hot water is necessary, as geothermal fluid often contains chemical  contaminants. In such cases heat exchangers are utilised to extract the heat  from the hot geothermal fluid and transfer it to either clean water, or in the  case of drying processes, to air.  
                  
                  There  are two main types of heat exchangers commonly used. They are plate heat  exchangers and shell and tube. The heat exchanger technology employed in the  geothermal industry is the same as is commonly used over a wide range of industries  where heat exchangers are utilised. Commonly used heat pump technology can also  be employed in order to utilise geothermal heat for air conditioning and  refrigeration applications.  
                 
                    9. Technological Issues with Geothermal Developments 
                        Whether geothermal energy is utilized for power  production or for direct use applications, there are issues in geothermal  utilization that often have technical implications. 
                       
                  
                    Geothermal fluids often contain significant quantities of gases such as  hydrogen sulphide as well as dissolved chemicals and can sometimes be acidic.  Because of this, corrosion, erosion and chemical deposition may be issues,  which require attention at the design stage and during operation of the  geothermal project. Well casings and pipelines can suffer corrosion and /or  scale deposition, and turbines, especially blades can suffer damage leading to  higher maintenance costs and reduced power output.  
                  
                    However,  provided careful consideration of such potential problems is made at the design  stage, there are a number of technological solutions available. Such potential  problems can be normally overcome by a combination of utilising corrosion  resistant materials, careful control of brine temperatures, the use of steam  scrubbers and occasionally using corrosion inhibitors. 
                  
                    Provided  such readily available solutions are employed, geothermal projects generally  have a very good history of operational reliability. Geothermal power plants  for example, can boast of high capacity factors (typically 85-95%)                    With all projects of significant size, geothermal  projects are developed through a series of logical stages, which may be  summarized in the Geothermal Development Flow Chart. This figure shows the  various stages in a typical geothermal project. Decisions to proceed to the  next stage are normally made progressively through out the project. 
                    
                  Reconnaissance  and Exploration 
                    Geothermal resources are usually located and  defined by a progressively more intensive (and expensive) exploration programme  that starts at a regional level and eventually results in a drilling program to  positively delineate the resource.  
                  
   Reconnaissance surveys will  identify the most suitable prospect areas by recognition of favourable  geological settings and locating any hot    springs or other surface thermal discharge.  Reconnaissance studies involve mapping any hot springs or other surface thermal features  and the identification of favourable geological structures. The chemical  composition of the discharging fluids reveals information about the deeper  reservoir, including temperature and fluid characteristics. Geological studies  provide information about the probable distribution and extent of aquifers, as  well as the likely heat source and heat flow regime. Areas identified as having  high potential or that are favoured because of proximity to an energy use  centre, will be explored by more comprehensive scientific survey methods. In  addition to more detailed geological and geochemical studies, a range of  geophysical techniques may be used including gravity, magnetic and resistivity  surveys. Resistivity surveys in particular can locate anomalies that are  directly related to the presence of geothermal fluids. Interpretation of these  integrated geoscientific studies leads to prioritisation of targets for  exploration drilling programmes. The application of sound scientific method and  analysis during these early phases increases the probability of success with  subsequent drilling and development. If these surveys provide very good  indications for the presence of a useful geothermal reservoir, the resource is  tested by the drilling of exploration wells so that actual subsurface  temperatures can be measured and reservoir productivity tested. The exploration  programme should therefore be designed to suit the type of resource expected,  the amount of energy expected to be produced from the project and the timeframe  for the development.  
                  
                    10.  Application of Chemical techniques in geothermal exploration 
                  The application of chemical techniques has become  an integral part of any geothermal exploration programme. During the  pre-drilling stages of exploration, geochemistry of thermal waters and gases  may provide information on deep conditions and processes not obtainable by  geological or geophysical techniques.  The dissolved constituents in the  thermal waters can be grouped into two major groups i.e.  a)  Chemically, non-reactive and  b) chemically reactive groups. The  first group may be called tracers and the second, the geo-indicators. 
                  
                  The tracers, once enter the fluid phase, ideally  remain unchanged, providing a tag allowing their origin to be traced back to  their. These include noble gases like He and Ar and other conservative elements  like Cl, Li, B, Rb, Cs and N2. 
                  
                  Geo-indicators are reactive species, responding  to changes in their environment (especially temperature and type of rock with  which the fluids interact) in a controlled and well understood manner. These  include Na, K, Mg, Ca and SiO2, which take part in temperature  dependent reactions with Al-silicate rocks which house geothermal systems, and  H2, H2S, CH4 and CO2 which are  involved in temperature -pressure dependent redox reactions within them or  redox systems of the rock phase such as Fe(II)/Fe(III) reaction. 
                  
                  Out of the constituents mentioned above, Na, K,  Mg, Ca, SiO2, Cl, Li, B, Rb and  Cs enter the liquid phase  while He, Ar H2, H2S, CH4 and CO2  enter the vapour phase in geothermal systems. These constituents are very  useful in estimating the thermal reservoir conditions and the reservoir  temperature. We shall see how these constituents are used in estimating the  reservoir temperature. Those chemical constituents that are used in  estimating the reservoir temperature are known as geochemical thermometers. Two  such important geothermometers, the silica and cation geothermometers are  discussed below. They are known as water geothermometers because they enter the  liquid phase in geothermal systems. 
                  
                    11.  Silica and Cations as  geothermometers 
                    Water geothermometers are classified into two  groups i.e. 1) based on temperature dependent variations in solubility of  individual minerals and 2) based on temperature dependent exchange reactions  which fix the ratios of certain dissolved constituents (Fournier, 1991).   The silica minerals are ideal members under group 1 while other cations such as  Ca, Mg, Na and K are ideal under group 2. Temperature estimation based on  group 2 members require evaluation of activity coefficients for two or  more dissolved species in order to calculate the temperature at which solution-mineral  equilibrium was last attained. The calculation of activity coefficients must  take into account the total composition of the fluid and the result vary as a  function of temperature. Simple techniques for estimating the reservoir  temperatures based on silica and cations are described here. 
                  
                    11.1a Silica geothermometer 
                    The solubility of silica mineral decreases  drastically and linearly as temperature decreases below 340oC. If  temperature vs silica concentration in thermal waters are plotted, they define  a straight line within this temperature limits. Similarly the dissolved silica  in liquid after steam separation (90 - 250oC) also defines a  similar line.  The equations for such straight lines results in the  following equations: 
                  
                    Quartz -no steam loss                        to C = (1309/5.19 - log S) -  273.15         (1)
                    Quartz -max steam  loss                    to C = (1522/5.75 - log S) -  273.15         (2) 
                  
   The above two equations are extensively  been used for calculating geothermometer temperatures in the range  of 100 - 250oC. However (Fournier, 1991).  
                  
                    11.1b Silica- enthalpy diagram 
                    It is useful to use enthalpy instead of  temperature in the silica- temperature diagrams to estimate the reservoir  temperatures. This is because, the combined heat contents (enthalpies) of two  types of waters at different temperatures are conserved when they mix, and thus  the dilution effect is eliminated here. Enthalpy-silica diagrams can be used to  correct silica concentrations for adiabatic cooling with single stage steam  loss at any temperature.   
                  
                    11.2  Cation geothermometers 
                    Cation geothermometers are widely used to  calculate the reservoir temperatures from surface thermal waters. This  technique is based on ion exchange reactions with temperature dependent  equilibrium constants. An example is the exchange of Na and K between  co-existing alkali feldspars: 
                  
                                 Na Al Si3 O8 +  K   =   K Al Si3  O8   
                  
                    The equilibrium constant Keq for the above reaction is
                     
                  The above equation can be written as   
                  
                                Keq    =   Na / K    -   4 
                  
                    Similar equation can be written for  monovalent and divalent ions such as K and Mg, thus 
                                                 Keq    = K / Mg    - 5 
                  
                    The variation of Keq with temperature can be  obtained by an integrated form of van't Hoff equation 
                  
                                 Log  Keq  =   1 Ho / 2.303 RT + C    - 6  
                  
                    Where 1 Ho  is  the enthalpy of the reaction, T is temperature in Kelvin, R is the gas constant  and C is a constant of integration. 
                  
                    Since 1  Ho  changes little with temperature in the range of 0 to 300oC,  a plot of log Na/K versus temperature will approximately be a  straight line.  Equations for straight line, like that developed for silica  geothermometery have been proposed by several workers and two most widely used  equations are given below: 
                  Equation 5 is proposed by Fournier (1983) and 6  is proposed by Giggenbach et al., (1983). Besides these two, several other  equations such as  Na-K-Ca and K-Ca, Na -Ca and  K- Mg  have  also been proposed and are in use. Giggenbach (1988) evolved a new  geothermometer where both K/Na (t kn)  and K/Mg (t km) geothermometers are combined. This geothermometer,  represented in the form a figure by Giggenbach (1988) is wide used for the  above purpose. Selecting suitable thermal water samples is very essential in  estimating reservoir temperatures using geochemical thermometers. 
                   
                    13.  Indian Geothermal Provinces 
                    In India nearly 400 thermal springs  occur, distributed in seven geothermal provinces. These provinces include The  Himalayas: Sohana: West coast; Cambay: Son-Narmada-Tapi (SONATA):   Godavari and Mahanadi.  These springs are  perennial and their surface temperature range from 37 to 90o  C with a cumulative surface discharge of over 1000 l/m. Figure 7  shows the location of these geothermal provinces.  These provinces  are associated with major rifts or  subduction tectonics and registered  high heat flow and  high geothermal gradient (Figure 7)  For example  the heat flow values and thermal gradients of  these provinces are 468  mW/m2; 234o C/km (Himalayas); 93 mW/m2; 70o  C/km (Cambay); 120 - 260 mW/m2; 60-90o C/km (SONATA); 129  mW/m2; 59o C/km (west coast); 104 mW/m2; 60o  C/km (Godavari) and  200 mW/m2; 90o C/km (Bakreswar,  Bihar). The reservoir temperature estimated using the above described  geothermometers are 120o C (west coast), 150o C  (Tattapani) and 200o C (Cambay). The depth of the reservoir in these  provinces is at a depth of about 1 to 2 km (Chandrasekharam, 2000; Minissale et  al., 2000 and references therein: see web: dchandra.hypermart.net).  These geothermal systems are liquid dominated and steam dominated systems  prevail only in Himalayan and Tattapani geothermal provinces. The issuing  temperature of water at Tattapani is 90o C; at Puga (Himalaya) is 98o  C and at Tuwa (Gujarat) is 98o C.  The power generating capacity of these thermal springs is about 10,000 MW (Ravi  Shanker, 1996). These are, as mentioned above, medium enthalpy resources. From  the point of power generation technology described above in Part I, these  resources can be utilized effectively to generate power using binary cycle  method.  Since majority of these springs are located in rural India,  these springs can support small scale industries in such areas. Dehydrated  vegetables and fruits have a potential export market and India being an agricultural country, this  industry is best suited for India  conditions. An example of the cost involved in dehydration of fruits using  conventional heat and geothermal heat, from Central   America, is given in the following below table. This gives an  idea about the economic potential of geothermal resource. 
                  Table  showing the cost of dehydrated fruits using conventional and geothermal heat 
                  
                    
                      | Products  | 
                       Capacity(Kg)   | 
                      Time (hours)  | 
                      Heat Cost 
                       | 
                      Heat Cost 
                       | 
                     
                    
                          | 
                         | 
                         | 
                      Geothermal Sys.  | 
                      Convential Sys.  | 
                     
                    
                       Pineapple   | 
                      800   | 
                      18   | 
                      900   | 
                      5000   | 
                     
                    
                       Apple (Slices)   | 
                      700   | 
                      16   | 
                      800   | 
                      4500   | 
                     
                    
                       Apple    (Cubes)   | 
                      900   | 
                      16   | 
                      800   | 
                      4500   | 
                     
                    
                       Banana   | 
                      800   | 
                      24   | 
                      1300   | 
                      6000   | 
                     
                    
                       Plantain   | 
                      700   | 
                      30   | 
                      1500   | 
                      6500   | 
                     
                   
                                                                        Courtesy: M/s Eco-Fruit Agro Industry,Gautimala, Central America (Cost in rupees) 
                   Map showing Indian geothermal provinces  with heat flow and geothermal gradients     
                    
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